Deuterium isotope effects in the solvolysis of benzal halides. 3. beta. -D/sub 3/ isotope effects and the mechanism of solvolysis of 1,1-dihaloethylbenzenes in dioxane-water mixtures

Journal Article · Wed Nov 23 04:00:00 EST 1977 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00466a075· OSTI ID:5218467

Sridharan, S; Vitullo, V P

The ..beta..-D/sub 3/ isotope effects and product distributions in the solvolysis of 1,1-dihaloethylbenzenes in dioxane--water mixtures were determined. The reaction yields two products and the rate-limiting step was determined. The factors determining the extent of elimination reactions are discussed. (JSR)

• Research Organization: Univ. of Maryland, Baltimore
• OSTI ID: 5218467
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 99:24; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
AROMATICS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
DEUTERIUM
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
REACTION KINETICS
SOLVOLYSIS
STABLE ISOTOPES