Catalytic effects in the reaction of polypropylene with benzoyl peroxide and structural-kinetic model of the polymer

Journal Article · Tue Sep 01 04:00:00 EDT 1987 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:5217557

Mikheev, Yu A; Guseva, L N; Toptygin, D Ya

The kinetic peculiarities of the chain arylation of polypropylene with benzoyl peroxide and the yields of the transformation products (arylated polypropylene benzene, and benzoic acid) were established. The equation of the reaction rate depends on the way in which the samples were prepared and on the benzoyl peroxide concentration in the polymer. The kinetic peculiarities found were explained by a heterophase mechanism.

• Research Organization: Institute of Chemical Physics, Moscow (USSR)
• OSTI ID: 5217557
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:2; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
ARYLATION
BENZOIC ACID
BENZOYL PEROXIDE
CARBOXYLIC ACIDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
EQUATIONS
HETEROGENEOUS CATALYSIS
KINETIC EQUATIONS
KINETICS
MATHEMATICAL MODELS
MOLECULAR STRUCTURE
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PEROXIDES
POLYMERS
POLYOLEFINS
POLYPROPYLENE
REACTION KINETICS
YIELDS