The single electron chemistry of coals
The objective of this work is to investigate and characterize the single electron reactions of alkyl and alkoxy aromatic compounds in order to determine the role these reactions play in the chemistry of coal. Activities carried out in this reporting period are as follows: (1) attempts will be made to demonstrate that the radicals from inertinite maceral group will initiate the polymerization of 4-vinylpyridine; (2) the molecule, N,N-diphenyl-phenylenediamine, will be deposited in coals to characterize their native free radicals; (3) tetracyanoquinodimethane (TCNQ) and tetracyanoethylene (TCNE) will be used to characterize the numbers and strengths of single electron donors in coals. 7 refs., 4 tabs.
- Research Organization:
- Lehigh Univ., Bethlehem, PA (United States). Dept. of Chemistry
- Sponsoring Organization:
- DOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG22-89PC89785
- OSTI ID:
- 5215532
- Report Number(s):
- DOE/PC/89785-7; ON: DE92001651
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
010600* -- Coal
Lignite
& Peat-- Properties & Composition
ALKYL RADICALS
ALKYLATED AROMATICS
AROMATICS
AZINES
BINDING ENERGY
CARBONACEOUS MATERIALS
CHEMICAL REACTIONS
COAL
DOCUMENT TYPES
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ENERGY SOURCES
ETHERS
FERMIONS
FOSSIL FUELS
FUELS
HETEROCYCLIC COMPOUNDS
INERTINITE
LEPTONS
MACERALS
MATERIALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
POLYMERIZATION
PROGRESS REPORT
PYRIDINES
RADICALS
VALENCE
VINYL RADICALS
010600* -- Coal
Lignite
& Peat-- Properties & Composition
ALKYL RADICALS
ALKYLATED AROMATICS
AROMATICS
AZINES
BINDING ENERGY
CARBONACEOUS MATERIALS
CHEMICAL REACTIONS
COAL
DOCUMENT TYPES
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ENERGY SOURCES
ETHERS
FERMIONS
FOSSIL FUELS
FUELS
HETEROCYCLIC COMPOUNDS
INERTINITE
LEPTONS
MACERALS
MATERIALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
POLYMERIZATION
PROGRESS REPORT
PYRIDINES
RADICALS
VALENCE
VINYL RADICALS