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Processes of atmospheric deposition of metals and acids to forests

Conference ·
OSTI ID:5206365
We quantified the atmospheric deposition of the water-leachable fractions of trace metals to upper canopy foliage, determined the major mechanisms of deposition, and assessed the interactions between deposited metals and acid rain for several forested areas. Atmospheric sources contributed significantly to the annual flux of these elements to the forest floor in Walker Branch Watershed, Tennessee; deposition supplied from 14% (Mn) to approx. 40% (Cd, Zn) to approx. 99% (Pb) to this flux. The measured water solubility of these metals in suspended and deposited particles indicated that they may be readily dissolved following deposition; however, only Pb appeared to be absorbed directly at the leaf surface. Dry deposition constituted a major fraction of the total annual atmospheric input of Cd and Zn (approx. 20%), Pb, (approx. 55%), and Mn (approx. 90%). In southern forests, interactions between dry deposition and acid rain can result in concentrations of metals and H+ on leaves considerably higher than in rain alone. In the subalpine forests of New England cloud deposition can also contribute to increased ion concentration on leaves.
Research Organization:
Oak Ridge National Lab., TN (USA)
DOE Contract Number:
W-7405-ENG-26
OSTI ID:
5206365
Report Number(s):
CONF-820627-11; ON: DE82017442
Country of Publication:
United States
Language:
English