Low-temperature sup 3 He NMR studies in aged palladium tritide
- EG G Mound Applied Technologies, Miamisburg, Ohio (USA)
- Sandia National Laboratories, Livermore, California (USA)
Experimental results from a NMR study of {sup 3}He in nanometer-sized microbubbles in aged palladium tritide over the temperature range 4--300 K are presented. A determination of the rigid-lattice--line-shape second moment at 4 K provides a value for the density of {sup 3}He that is in good agreement with the value inferred for the same sample from an analysis of {sup 3}He spin-lattice relaxation data over the range 50--300 K. This latter analysis is based on the hypothesis of a melting transition for a distribution of densities, and assumes that the bulk helium equation of state applies to helium in the nanometer-sized bubbles. This latter assumption is supported by the agreement between the two independent density determinations. Line-shape analyses reveal narrowing of the {sup 3}He spectrum at about 35 K, which agrees with a prediction of motional narrowing based on an extrapolation of {sup 3}He diffusivity data determined over the range 100--250 K in an earlier study of aged palladium tritide. The observation of coexisting broad and narrow components in the free-induction decay at 40 K provides direct evidence for a distribution of {sup 3}He densities in aged palladium tritide. Because the melting temperature and the rigid-lattice second moment are both strong functions of density, the NMR techniques described here provide a sensitive measure of the density distribution and related properties.
- DOE Contract Number:
- AC04-88DP43495
- OSTI ID:
- 5205627
- Journal Information:
- Physical Review, B: Condensed Matter; (United States), Journal Name: Physical Review, B: Condensed Matter; (United States) Vol. 44:9; ISSN PRBMD; ISSN 0163-1829
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
360206* -- Ceramics
Cermets
& Refractories-- Radiation Effects
AGING
BUBBLES
DIFFUSION
EQUATIONS
EQUATIONS OF STATE
EVEN-ODD NUCLEI
HELIUM 3
HELIUM ISOTOPES
HYDRIDES
HYDROGEN COMPOUNDS
ISOTOPES
LIGHT NUCLEI
LOW TEMPERATURE
MAGNETIC RESONANCE
MEDIUM TEMPERATURE
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUCLEI
PALLADIUM COMPOUNDS
PALLADIUM HYDRIDES
RADIATION EFFECTS
RELAXATION
RESONANCE
SPECTRA
SPIN-LATTICE RELAXATION
STABLE ISOTOPES
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPOUNDS
TRITIDES
TRITIUM COMPOUNDS
ULTRALOW TEMPERATURE
VERY LOW TEMPERATURE