Synthesis gas conversion to gasoline range hydrocarbons over medium pore zeolite catalysts containing 3d-metals and bimetallics

Conference · Mon Jan 01 04:00:00 EST 1979 · Am. Chem. Soc., Div. Fuel Chem., Prepr.; (United States)

OSTI ID:5204357

Rao, V U.S. ^[1]; Gormely, R J; Pennline, H W; Schneider, L C; Obermyer, R

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1. Pittsburgh Energy Technology Center, PA

Our experiments lead to the following conclusions: (1) Zeolite acidity plays an important role in the formation of aromatics from synthesis gas by bifunctional catalysts as strikingly evidenced in a comparison of the product slates from ZSM-5 (11.1% Fe) and Silicalite (13.6% Fe). (2) The transition metal component impregnated into the zeolite plays an important role in selectivity as seen from the liquid phase products from ZSM-5 (11.1% Fe) and ZSM-5 (5.6% Fe, 4.5% Co). In this context, zeolites containing bimetallic clusters are of special interest. (3) Silicalite impregnated with Fe and promoted with K has an exceptionally high selectivity for the production of C/sub 2/-C/sub 4/ olefins from synthesis gas.

• OSTI ID: 5204357
• Report Number(s): CONF-800303-P3
• Conference Information: Journal Name: Am. Chem. Soc., Div. Fuel Chem., Prepr.; (United States) Journal Volume: 25:2
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010404* -- Coal
Lignite
& Peat-- Gasification
010405 -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
ANTIKNOCK RATINGS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COAL GASIFICATION
DATA
DATA FORMS
ELEMENTS
EXPERIMENTAL DATA
FISCHER-TROPSCH SYNTHESIS
FLUIDS
FUELS
GASES
GASIFICATION
GASOLINE
INFORMATION
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
METALS
MINERALS
NUMERICAL DATA
PETROLEUM PRODUCTS
SPECIFICITY
SYNTHESIS
SYNTHESIS GAS
TABLES
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENTS
ZEOLITES