Radiative transition probabilities for the A /sup 1/. sigma. --X /sup 1/. sigma. /sup +/ bands of /sup 7/LiH. [Tables]

Technical Report · Sat Jan 01 04:00:00 EST 1977

DOI:https://doi.org/10.2172/5202179· OSTI ID:5202179

Zemke, W T; Stwalley, W C

The recently reported (J. Chem. Phys. 66, 5412 (1977)) hybrid potential curves for the X /sup 1/..sigma../sup +/ and A /sup 1/..sigma../sup +/ states of LiH are combined with the ab initio transition moments of Docken and Hinze (J. Chem. Phys. 57, 4936 (1972)) to calculate radiative transition probabilities between all upper (v' < or = 26) and all lower (v'' < or = 23) vibrational levels of /sup 7/LiH. By far the strongest single band found is the 23 to 26 band between the highest ''long-range'' levels in each potential. A comparison with experimental intensity observations is made; it appears that the experiments are globally in accord with calculations, but with some detailed differneces discussed herein.

• Research Organization: Wartburg Coll., Waverley, Iowa (USA). Dept. of Chemistry; Iowa Univ., Iowa City (USA)
• OSTI ID: 5202179
• Report Number(s): COO-2326-22
• Country of Publication: United States
• Language: English

Related Subjects

640302* -- Atomic
Molecular &amp; Chemical Physics-- Atomic &amp; Molecular Properties &amp; Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKALI METAL COMPOUNDS
ALKALI METAL ISOTOPES
BAND THEORY
ENERGY
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
ISOTOPES
LIGHT NUCLEI
LITHIUM 7
LITHIUM COMPOUNDS
LITHIUM HYDRIDES
LITHIUM ISOTOPES
NUCLEI
ODD-EVEN NUCLEI
POTENTIAL ENERGY
STABLE ISOTOPES
TABLES
VIBRATIONAL STATES