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Title: Distillation technology increases propane recovery in carbon-dioxide floods

Journal Article · · Oil Gas J.; (United States)
OSTI ID:5194838

Carbon-dioxide-rich separator gas streams from CO/sub 2/ floods can be processed by the Ryan/Holmes propane-recovery method to obtain propane recoveries of 85-95%. The Ryan/Holmes processes are a family of distillations which use recycle additive to make possible or aid separation of certain components. Recycle additive, derived from NGL present in the feed, is a C/sub 4/ + stream. It is introduced to the Ryan/Holmes columns at or near the top of the fractionators. Previously presented was the separation of methane and CO/sub 2/, in which additive operates to prevent freezing and to raise the temperatures required for the separation. Indeed, even at propane-refrigeration temperatures, a perfect separation between methane and CO/sub 2/ can be accomplished. The second separation is carbon dioxide and ethane. These two compounds form an azeotrope; additive breaks the azeotrope and permits ethane recovery. The third separation is CO/sub 2/ and H/sub 2/S. In the absence of additive, their separability is weak; separation is greatly enhanced by the presence of additive.

Research Organization:
Koch Process Systems Inc., Westborough, MA
OSTI ID:
5194838
Journal Information:
Oil Gas J.; (United States), Vol. 84:40
Country of Publication:
United States
Language:
English