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U.S. Department of Energy
Office of Scientific and Technical Information

Bioremediation of Hanford groundwater

Conference ·
OSTI ID:5192126
Liquid wastes containing radioactive, hazardous, and regulated chemicals have been generated throughout the 40 years of operations at the U.S. Department of Energy's (DOE) Hanford Site. Some of these wastes were discharged to the soil column and many of the waste components, including nitrate (NO3-), carbon tetrachloride (CCl4), and several radionuclides, have been detected in the Hanford groundwater. Current DOE policy prohibits the disposal of contaminated liquids directly to the environment, and remediation of existing contaminated groundwaters may be required. A research and development program is underway to develop bioremediation technologies for both ex situ and in situ groundwater treatment. Although ex situ pump-and-treat remediation schemes have been criticized recently for their limited effectiveness in cleaning up contaminated aquifers to stringent regulatory standards, the use of extraction wells and above ground treatment can be effective in removing bulk quantities of contaminants from the subsurface. Extraction processes can also be used on an interim basis to control the migration of contaminants. An ex situ bioremediation technology is being developed to provide cost effective methods for treating extracted groundwater. An in situ treatment process is also being developed. The goal of this process is to stimulate the native microorganisms and accelerate the natural degradation of NO3- and CCl4. In situ treatment offers the additional benefits of lower operating costs, better removal of sorbed contaminants, and lower potential for exposure of workers to hazardous chemicals. A demonstration site at Hanford for in situ biological treatment was selected in 1990, and extensive hydrological, chemical, and biological characterization of the site is underway. Current research and development activities are focusing on developing methods for supplying nutrients to the subsurface, evaluating the effect of in situ bioremediation on the long-term mobility of metal and radionuclide co-contaminants, and modeling the bioremediation process using three-dimensional visualization tools to help design the field-scale demonstration site and predict performance. The in situ bioremediation process will be developed and tested at the laboratory and intermediate-scale prior to field demonstration as part of the DOE's Integrated Demonstration for Cleanup of Volatile Organic Compounds at Arid Sites (VOC-Arid Integrated Demonstration).
Research Organization:
Pacific Northwest Laboratory (PNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC06-76RL01830
OSTI ID:
5192126
Report Number(s):
PNL-SA--19646; CONF-910981--25; ON: DE92000799
Country of Publication:
United States
Language:
English