Angular-overlap calculation of the Jahn-Teller stabilization energie for f-orbital degeneracies

Journal Article · Sat Mar 01 04:00:00 EST 1980 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic50205a016· OSTI ID:5183982

Warren, K D

The angular-overlap model is applied to the calculation of the linear Jahn-Teller coupling constants for f-orbital degeneracies. The MX/sub 6/, O/sub h/, chromophore is treated as representative of the highest symmetry commonly occurring in the lanthanide and actinide series, and it is shown that, even when spin-orbit effects are taken into account, 5f orbital degeneracies may lead to significant Jahn-Teller stabilization energies. The operation of this effect for F/sup 1/ GAMMA/sub 8/ states is considered. 2 tables.

• Research Organization: University Coll., Cardiff, Wales
• OSTI ID: 5183982
• Journal Information: Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 19:3; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400702 -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPOUNDS
ACTINIDES
ALKALI METAL COMPOUNDS
ANGULAR MOMENTUM
BROMIDES
BROMINE COMPOUNDS
CESIUM CHLORIDES
CESIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
COUPLING CONSTANTS
ELEMENTS
ENERGY LEVELS
EXCITED STATES
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
IODIDES
IODINE COMPOUNDS
JAHN-TELLER EFFECT
METALS
ORBITAL ANGULAR MOMENTUM
PROTACTINIUM BROMIDES
PROTACTINIUM CHLORIDES
PROTACTINIUM COMPOUNDS
PROTACTINIUM FLUORIDES
PROTACTINIUM IODIDES
RARE EARTHS
STABILIZATION
URANIUM BROMIDES
URANIUM CHLORIDES
URANIUM COMPOUNDS
URANIUM FLUORIDES
URANIUM HEXAFLUORIDE