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New layered compounds with the general composition (MO) (CuSe), where M = Bi, Nd, Gd, Dy, and BiOCuS: Syntheses and crystal structure

Journal Article · · Journal of Solid State Chemistry
; ;  [1]
  1. Moscow State Univ. (Russian Federation); and others
The syntheses of four new copper oxyselenides with the general formula (MO)(CuSe)(M = Bi, Nd, Gd, Dy) and one copper oxysulfide, BiOCuS, are reported. The tetragonal unit cell dimensions of all compounds are given. A new bismuth-copper oxyselenide, BiOCuSe, has been structurally characterized from powder X-ray diffraction data and finally solved by the Rietveld profile method with R{sub 1} = 0.069. The BiCuSeO crystal structure is formed by alternating [Bi{sub 2}O{sub 2}] and [Cu{sub 2}Se{sub 2}] layers.
OSTI ID:
518209
Journal Information:
Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 1 Vol. 112; ISSN 0022-4596; ISSN JSSCBI
Country of Publication:
United States
Language:
English

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