Characterization of some autoionization resonances in CO/sub 2/ using triply differential photoelectron spectroscopy

Journal Article · Thu Jul 01 00:00:00 EDT 1982 · J. Chem. Phys.; (United States)

OSTI ID:5168166

Parr, A C; Ederer, D L; Dehmer, J L; Holland, D M.P.

We report vibrationally resolved branching ratios and asymmetry parameters for two sets of autoionizing resonances in CO/sub 2/ near 680 and 750 A. These resonances were excited with monochromatized synchrotron radiation from the National Bureau of Standards storage ring and the energy and angle of ejection of the photoelectrons were analyzed. The results show striking non-Franck--Condon behavior.

• Research Organization: Synchrotron Ultraviolet Radiation Facility, National Bureau of Standards, Washington, D.C. 20234
• OSTI ID: 5168166
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 77:1; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AUTOIONIZATION
BRANCHING RATIO
BREMSSTRAHLUNG
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
ELECTROMAGNETIC RADIATION
ELECTRON SPECTROSCOPY
ENERGY LEVELS
EXCITED STATES
IONIZATION
OXIDES
OXYGEN COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
RADIATIONS
SPECTROSCOPY
SYNCHROTRON RADIATION
VIBRATIONAL STATES