Energies of organic compounds. [Polyoxygenated methanes, ketals, orthoesters, cyclopropane derivatives]

Technical Report · Tue Jul 01 04:00:00 EDT 1980

DOI:https://doi.org/10.2172/5166625· OSTI ID:5166625

Wiberg, K. B.

Automatic reaction calorimeters were developed. Enthalpies of hydration or hydrolysis were determined for polyoxygenated methanes, ketals, acetals, orthoesters, and alkenes. Trifluoroacetolysis of alkenes was carried out. Enthalpies of acetolysis and combustion of cyclopropane derivatives were also determined. Molecular mechanics calculations were carried out for ketones and ketals. Charge distribution in organic compounds were studied. 31 references. (DLC)

• Research Organization: Yale Univ., New Haven, CT (USA). Dept. of Chemistry
• Sponsoring Organization: USDOE
• DOE Contract Number: AS02-76ER04060
• OSTI ID: 5166625
• Report Number(s): DOE/ER/04060-T1
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACETALS
ALKANES
ALKENES
CALORIMETERS
CHEMICAL REACTIONS
COMBUSTION HEAT
CYCLOALKANES
DECOMPOSITION
ELECTRIC CHARGES
ENERGY
ENTHALPY
ESTERS
ETHERS
HEAT
HYDROCARBONS
HYDROLYSIS
LYSIS
MEASURING INSTRUMENTS
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
REACTION HEAT
RESEARCH PROGRAMS
SOLVOLYSIS
THERMODYNAMIC PROPERTIES