Forest soil organic horizon acidification: Effects of temperature, time, and solution/soil ratio

Technical Report · Fri Jan 01 04:00:00 EST 1988

OSTI ID:5164468

James, B R; Riha, S J

A forest soil organic horizon (Oe) was acidified with HNO{sub 3} (0-5 cmol/kg) in the laboratory at three solution/soil ratios (10, 50, 100), three temperatures (4, 14, 30 C), and for up to 162 h to compare effects to added H{sup +} on pH, soluble Ca, Al, and C with effects of environmental conditions likely to vary seasonally in the forest floor. Soil suspension pH reached a steady state within 48 h, regardless of quantity of H{sup +} added, solution/soil ratio, or temperature. Calcium concentrations also reached a steady state with soil solid phases quickly, and additions of H{sup +} increased quantities of Ca (mmol/kg) in solution as did increasing solution/soil ratio. Shaking time and temperature had smaller effects on Ca than did H{sup +} additions and solution/soil ratio. In contrast, reactions controlling dissolved organic carbon (DOC) and total soluble aluminum (Alt) were slower than those for pH and Ca. Quantities of DOC and Al going into solution remained nearly constant, so that increasing the solution/soil ratio diluted concentrations. Dissolved organic C and soluble Al increased with longer shaking times and higher temperature. The results have implications for designing realistic laboratory experiments on forest floor acidification, for evaluating seasonal and yearly variations in soil/solution composition in the field, and in developing accurate and reliable simulation models of H+ reactions in forest soils.

• Research Organization: Cornell Univ., Ithaca, NY (USA)
• OSTI ID: 5164468
• Report Number(s): PB-90-103094/XAB
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
540120 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
540220* -- Environment
Terrestrial-- Chemicals Monitoring & Transport-- (1990-)
ACID RAIN
ACIDIFICATION
ALKALINE EARTH METALS
ALUMINIUM
ATMOSPHERIC PRECIPITATIONS
CALCIUM
CARBON
CHEMISTRY
DEPOSITION
DISPERSIONS
ELEMENTS
FORESTS
MATTER
METALS
MIXTURES
NAPAP
NONMETALS
ORGANIC COMPOUNDS
PH VALUE
RAIN
SOIL CHEMISTRY
SOLUTIONS
TIME DEPENDENCE
VOLATILE MATTER