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Demonstration of a maximum recycle, sidestream softening system at a petrochemical plant

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OSTI ID:5158521

The purpose of this study was to delineate the performance of maximum recycle, sidestream softening system at the USS Chemicals plant in Houston, Texas. The system is composed of two lime softening units that treat the blowdown from the cooling water system. The softeners remove the calcium, magnesium, silica, and carbonate ions. The water is then processed through a recarbonator and filter for return to the cooling water system. Various process effluents from the petrochemical units are treated and added to the cooling water. The only liquid discharge from the plant is the high salt content spent demineralizer regeneration water. The major problem discovered was biofouling in the heat transfer system caused by high concentrations of organic materials in the cooling water. Softener operation was stabilized and improved during the study period. Other investigations included: the fate of carbon dioxide used for pH control in the cooling towers, the toxicity of the softener sludge, and the design of an emergency blowdown.

Research Organization:
Univ. of Houston, Houston, TX
OSTI ID:
5158521
Country of Publication:
United States
Language:
English