Effect of SiO[sub 2], NaCl, Al[sub 2]O[sub 3], and FeCl[sub 3] on phase change behavior of supported and unsupported TiO[sub 2]
Journal Article
·
· Journal of Solid State Chemistry; (United States)
The anatase-rutile phase change temperatures in TiO[sub 2] powders precipitated from aqueous TiCl[sub 4] and the same deposited on muscovite and phlogopite micas were investigated. Doping with Al[sub 2]O[sub 3], NaCl, and SiO[sub 2] increased the phase change temperature of supported and unsupported TiO[sub 2], but doping with FeCl[sub 3] 6H[sub 2]O decreased the beginning temperature of the phase change on unsupported TiO[sub 2]. The difference in phase change dependence on temperature between undoped TiO[sub 2] supported by mica substrate during the calcination step.
- OSTI ID:
- 5150941
- Journal Information:
- Journal of Solid State Chemistry; (United States), Journal Name: Journal of Solid State Chemistry; (United States) Vol. 106:2; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360202* -- Ceramics
Cermets
& Refractories-- Structure & Phase Studies
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYST SUPPORTS
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
CRYSTAL DOPING
HALIDES
HALOGEN COMPOUNDS
IRON CHLORIDES
IRON COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
SILICON COMPOUNDS
SILICON OXIDES
SODIUM CHLORIDES
SODIUM COMPOUNDS
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE
TEMPERATURE RANGE 1000-4000 K
TITANIUM COMPOUNDS
TITANIUM OXIDES
TRANSITION ELEMENT COMPOUNDS
360202* -- Ceramics
Cermets
& Refractories-- Structure & Phase Studies
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYST SUPPORTS
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
CRYSTAL DOPING
HALIDES
HALOGEN COMPOUNDS
IRON CHLORIDES
IRON COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
SILICON COMPOUNDS
SILICON OXIDES
SODIUM CHLORIDES
SODIUM COMPOUNDS
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE
TEMPERATURE RANGE 1000-4000 K
TITANIUM COMPOUNDS
TITANIUM OXIDES
TRANSITION ELEMENT COMPOUNDS