Inexpensive cross-linked polymeric separators made from water-soluble polymers

Journal Article · Mon Feb 01 04:00:00 EST 1982 · J. Electrochem. Soc.; (United States)

DOI:https://doi.org/10.1149/1.2123807· OSTI ID:5137598

Hsu, L C; Sheibley, D W

Polyvinyl alcohol (PVA) cross-linked chemically with aldehyde reagents produces membranes which demonstrate oxidation resistance, dimensional stability, low ionic resistivity (<0.8 /OMEGA/-cm/sup 2/), low zincate diffusivity (1x10/sup -7/ mols/cm/sup 2//-min), and low zinc dendrite penetration rate (>350 min) which make them suitable for use as alkaline battery separators. They are intrinsically low in cost, and environmental health and safety problems associated with commercial production appear minimal. Preparation, property measurements, and cell test results in Ni/Zn and Ag/Zn cells are described and discussed. 4 refs.

• Research Organization: NASA, Lewis Res Cent, Cleveland, Ohio
• OSTI ID: 5137598
• Journal Information: J. Electrochem. Soc.; (United States), Journal Name: J. Electrochem. Soc.; (United States) Vol. 129:2; ISSN JESOA
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
250903* -- Energy Storage-- Batteries-- Materials
Components
&amp; Auxiliaries
BATTERY SEPARATORS
CHEMICAL REACTIONS
CROSS-LINKING
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
MATERIALS
MEMBRANES
METAL-METAL OXIDE BATTERIES
NICKEL-ZINC BATTERIES
ORGANIC COMPOUNDS
ORGANIC POLYMERS
POLYMERIZATION
POLYMERS
SILVER-ZINC BATTERIES
ZINC COMPOUNDS
ZINCATES