Reformer-pressure swing adsorption process for the production of carbon monoxide
An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.
- Assignee:
- Union Carbide Corp., Danbury, CT
- Patent Number(s):
- US 4726816
- OSTI ID:
- 5135500
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
080103* -- Hydrogen-- Production-- Steam Reformer Processes
ADSORBENTS
ADSORPTION
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON MONOXIDE
CARBON OXIDES
CATALYSIS
CATALYSTS
CHALCOGENIDES
CHEMICAL REACTIONS
DEPRESSURIZATION
ELEMENTS
HYDROCARBONS
HYDROGEN
HYDROGEN PRODUCTION
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PRESSURIZING
PRODUCTION
RECYCLING
REFORMER PROCESSES
REMOVAL
SORPTION
STEAM REFORMER PROCESSES