Experimental aspects of solid-state voltammetry
Journal Article
·
· Analytical Chemistry (Washington)
- Univ. of North Carolina, Chapel Hill, NC (United States); and others
This paper describes the properties of poly(ether) polymer electrolytes as solvent media for solid-state voltammetry. Experimental requirements for microelectrode voltammetry and results for the dependency of diffusive transport of electroactive solutes on polymer solvent molecular weight, structure, and temperature (and related phase state) are described for eight poly(ether)s: linear poly(ethylene oxides) MW = 400, 1000, 2000, and 600 000 (Me{sub 2}PEG-400, Me{sub 2}PEG-1000, Me{sub 2}PEG-2000, PEO-600 000), linear poly(propylene oxide) MW = 4000 (PPO-4000), the comb polymer poly(bis[(methoxyethoxy)ethoxy]phosphazine) (MEEP), the block copolymer poly(ether)-poly(urethane urea)(PEUU), and the cross-linked poly(ether) network PEO. 28 refs., 10 figs., 1 tab.
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG05-87ER13675
- OSTI ID:
- 513382
- Journal Information:
- Analytical Chemistry (Washington), Journal Name: Analytical Chemistry (Washington) Journal Issue: 10 Vol. 64; ISSN 0003-2700; ISSN ANCHAM
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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· Chemistry of Materials; (United States)
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OSTI ID:7238924
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· Journal of the American Chemical Society; (USA)
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OSTI ID:6635982
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Thu Dec 31 23:00:00 EST 1987
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OSTI ID:6829700