Conductance studies of the alkali metal chlorides in aluminum chloride-propylene carbonate solution

Journal Article · Tue Jan 01 04:00:00 EST 1974 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100617a020· OSTI ID:5130465

Jorne, J; Tobias, C W

Conductance of the alkali metal chlorides, LiCl, NaCl, KCl, RbCl, CsCl, in unit molality solution of AlCl/sub 3/ in propylene carbonate was measured at 25 and 35/sup 0/. The measurements were performed in order to characterize the new process for the electrodeposition of the alkali metals at ambient temperature. The results have been interpreted in terms of solvation, ionic equilibrium, and the structure making-breaking ability of the alkali metals in AlCl/sub 3/ propylene carbonate solution. 2 figures, 7 tables.

• Research Organization: Lawrence Berkeley Lab., CA
• OSTI ID: 5130465
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 78:24; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
CARBONIC ACID DERIVATIVES
CESIUM CHLORIDES
CESIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
DEPOSITION
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
ELECTRODEPOSITION
ELECTROLYSIS
EQUILIBRIUM
HALIDES
HALOGEN COMPOUNDS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
LYSIS
MEDIUM TEMPERATURE
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
POTASSIUM CHLORIDES
POTASSIUM COMPOUNDS
RUBIDIUM CHLORIDES
RUBIDIUM COMPOUNDS
SODIUM CHLORIDES
SODIUM COMPOUNDS
SOLVATION
SURFACE COATING