Dinuclear {mu}-sulfido complexes of molybdenum with (dimethylamino)ethyl-substituted cyclopentadienyl ligands

Journal Article · Tue Apr 15 04:00:00 EDT 1997 · Organometallics

DOI:https://doi.org/10.1021/om9604637· OSTI ID:512903

Kaul, B B; Noll, B; Renshaw, S; DuBois, M R ^[1]

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1. Univ. of Colorado, Boulder, CO (United States)

The cyclopentadienyl ligand with the (dimethylamino)ethyl substituent has been used in the synthesis of the dinuclear {mu}-sulfido molybdenum complex (Me{sub 2}NCH{sub 2}CH{sub 2} CpMo({mu}-S)){sub 2}S{sub 2}-CH{sub 2}, 4, and related derivatives. Complex 4 has been isolated and characterized by spectroscopic methods as well as by an X-ray diffraction study. The structure confirms a bis({mu}-sulfido) derivative in which the dimethylamino substituents of the Cp ligands are directed away from the Mo{sub 2}S{sub 4} core. Protonation of 4 produces the dicationic complex with dimethylammonium substituents, which is soluble in water and other polar solvents. Reaction of 4 with [CuOTf]{sub 2}{center_dot}C{sub 6} leads to the formation of a copper adduct [(Me{sub 2}NCH{sub 2}CH{sub 2} CpMo({mu}-S)){sub 2}Cu(S{sub 2}CH{sub 2})]OTF, 6a. NMR studies of 6a in CD{sub 2}Cl{sub 2} suggest that the copper ion is stabilized by two sulfido ligands and by weakly coordinated dimethylamino groups. 26 refs., 2 figs., 2 tabs.

• OSTI ID: 512903
• Journal Information: Organometallics, Journal Name: Organometallics Journal Issue: 8 Vol. 16; ISSN ORGND7; ISSN 0276-7333
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
40 CHEMISTRY
CHEMICAL BONDS
LIGANDS
MOLECULAR STRUCTURE
MOLYBDENUM COMPLEXES
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANOMETALLIC COMPOUNDS
PROTONS
SYNTHESIS
X-RAY DIFFRACTION