Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction
The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and basic systems we have chosen for study in Task 3.
- Research Organization:
- SRI International, Menlo Park, CA (United States)
- Sponsoring Organization:
- DOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC21-85MC22065
- OSTI ID:
- 5128236
- Report Number(s):
- DOE/MC/22065-T16; ON: DE92017717
- Country of Publication:
- United States
- Language:
- English
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CARBONYLS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CONVERSION
DOCUMENT TYPES
ELEMENTS
FLUIDS
GASES
HYDROGEN COMPOUNDS
IRIDIUM
IRON COMPOUNDS
KINETICS
METALS
OXYGEN COMPOUNDS
PLATINUM METALS
PROGRESS REPORT
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RHODIUM
RUTHENIUM COMPOUNDS
SHIFT PROCESSES
SULFUR COMPOUNDS
SYNTHESIS GAS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
WATER