ESR spectrometry of short-lived radical pairs in solutions

Journal Article · Sun Nov 01 04:00:00 EST 1987 · J. Struct. Chem. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00753814· OSTI ID:5126447

Molin, Yu N; Anisimov, O A; Sagdeev, R Z

Methods of ESR spectrometry of short-lived radical pairs in solutions, based on magnetic-spin effects in chemical reactions, are reviewed in this article. These methods also make use of such phenomena as quantum beats in reactions of radical pairs, the effects of resonance microwave radiation on the yield in reactions of radical pairs, and stimulated nuclear polarization that appears with microwave pumping. The methods are distinguished by high sensitivity. Examples are given of the application of these methods in studying the structure and reactions of radical pairs in solutions.

• OSTI ID: 5126447
• Journal Information: J. Struct. Chem. (Engl. Transl.); (United States), Journal Name: J. Struct. Chem. (Engl. Transl.); (United States) Vol. 28:3; ISSN JSTCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ANGULAR MOMENTUM
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DISPERSIONS
DOCUMENT TYPES
ELECTROMAGNETIC RADIATION
ELECTRON SPIN RESONANCE
HYPERFINE STRUCTURE
MAGNETIC RESONANCE
MECHANICS
MICROWAVE RADIATION
MIXTURES
ORGANIC COMPOUNDS
ORIENTATION
PARTICLE PROPERTIES
QUANTUM MECHANICS
RADIATIONS
RADICALS
RECOMBINATION
RESONANCE
REVIEWS
SENSITIVITY
SOLUTIONS
SPIN
SPIN ORIENTATION
STRUCTURAL CHEMICAL ANALYSIS
YIELDS
ZEEMAN EFFECT