Thermodynamics of aqueous magnesium and calcium bicarbonates and mixtures with chloride
Journal Article
·
· J. Chem. Eng. Data; (United States)
The potential for the cell Pt,H/sub 2/,CO/sub 2/exclamationM(HCO/sub 3/)/sub 2/,MCI/sub 2/,CO/sub 2/(aq)exclamationAgCl,Ag with M = Mg and Ca was measured over a wide range of molalities at 298.15 K. The data were interpreted by the mixed-electrolyte equations of Pitzer and Kim to yield the ion-interaction parameters for Mg/sup 2 +/, HCO/sub 3//sup -/, and for Ca/sup 2 +/, HCO/sub 3//sup -/. The trace activity coefficients of M(HCO/sub 3/)/sub 2/ in MCI/sub 2/ and in NaCl are calculated.
- Research Organization:
- Department of Chemistry and Lawrence Berkeley Laboratory University of California, Berkeley, California
- OSTI ID:
- 5118626
- Journal Information:
- J. Chem. Eng. Data; (United States), Journal Name: J. Chem. Eng. Data; (United States) Vol. 30:1; ISSN JCEAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
25 ENERGY STORAGE
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
ALKALINE EARTH METAL COMPOUNDS
CALCIUM CARBONATES
CALCIUM CHLORIDES
CALCIUM COMPOUNDS
CALCIUM HALIDES
CARBON COMPOUNDS
CARBONATES
CHLORIDES
CHLORINE COMPOUNDS
ELECTROLYTES
EQUATIONS
HALIDES
HALOGEN COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
MAGNESIUM CARBONATES
MAGNESIUM CHLORIDES
MAGNESIUM COMPOUNDS
MEDIUM TEMPERATURE
OXYGEN COMPOUNDS
PLATINUM COMPOUNDS
SILVER CHLORIDES
SILVER COMPOUNDS
THERMODYNAMICS
TRANSITION ELEMENT COMPOUNDS
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
ALKALINE EARTH METAL COMPOUNDS
CALCIUM CARBONATES
CALCIUM CHLORIDES
CALCIUM COMPOUNDS
CALCIUM HALIDES
CARBON COMPOUNDS
CARBONATES
CHLORIDES
CHLORINE COMPOUNDS
ELECTROLYTES
EQUATIONS
HALIDES
HALOGEN COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
MAGNESIUM CARBONATES
MAGNESIUM CHLORIDES
MAGNESIUM COMPOUNDS
MEDIUM TEMPERATURE
OXYGEN COMPOUNDS
PLATINUM COMPOUNDS
SILVER CHLORIDES
SILVER COMPOUNDS
THERMODYNAMICS
TRANSITION ELEMENT COMPOUNDS