Angle resolved photoelectron spectroscopy of CS/sub 2/ and COS measured as a function of photon energy from 21 to 70 eV

Journal Article · Sun Aug 15 04:00:00 EDT 1982 · J. Chem. Phys.; (United States)

OSTI ID:5115672

Carlson, T A; Krause, M O; Grimm, F A

Data have been taken on both the partial cross sections and angular distribution parameters for the first five bands in CS/sub 2/ with a photon energy from 21 to 70 eV and for the first four bands of COS from 21 to 40 eV. The results are compared with calculations based on the multiple scattering method. In the case of photoionization of the 2..pi../sub g/ orbital of CS/sub 2/ and the 3..pi.. orbital of COS, the experimental results and calculations have been successfully explained in terms of the Cooper minimum. The behavior of the fifth band of CS/sub 2/ is accounted for by assigning it to a satellite peak arising from photoionization of the 2..pi../sub u/ orbital by way of configuration interaction. Comparison between the experimental results and calculations showed some problem areas, particularly with regard to the prediction of shape resonances, and suggestions are made for future improvement of the calculations.

• Research Organization: Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830
• OSTI ID: 5115672
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 77:4; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104* -- Spectral Procedures-- (-1987)
CARBON COMPOUNDS
CARBON OXIDES
CARBON SULFIDES
CHALCOGENIDES
CORRELATIONS
CROSS SECTIONS
DATA
DIFFERENTIAL CROSS SECTIONS
ELECTRON SPECTROSCOPY
ENERGY RANGE
EV RANGE
EV RANGE 10-100
INFORMATION
IONIZATION
MULTIPLE SCATTERING
NUMERICAL DATA
OXIDES
OXYGEN COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
RESOLUTION
RESONANCE
SCATTERING
SPECTROSCOPY
SULFIDES
SULFUR COMPOUNDS
THEORETICAL DATA