Abiotic transformations of halogenated organics. 1. Elimination reaction of 1,1,2,2,-tetrachloroethane and formation of 1,1,2-trichloroethene
Journal Article
·
· Environ. Sci. Technol.; (United States)
The abiotic homogeneous aqueous-phase elimination reaction of 1,1,2,2-tetrachloroethane to 1,1,2-trichloroethene has been studied. The reaction has been carried out in 0.100 M phosphate buffer in the pH range 5-9 and at 11 temperatures. In all cases, quantitative conversion of the 1,1,2,2-tetrachloroethane to 1,1,2-trichloroethene was observed. The reaction is second order overall and fits the equation log k/sub e/ = (15.87 +- 0.54) exp((-91.1 +- 3.4 kJmol)RT). 7 references, 3 figures, 2 tables.
- Research Organization:
- Florida International Univ., Miami (USA)
- OSTI ID:
- 5115126
- Journal Information:
- Environ. Sci. Technol.; (United States), Journal Name: Environ. Sci. Technol.; (United States) Vol. 21:11; ISSN ESTHA
- Country of Publication:
- United States
- Language:
- English
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Wed Jun 01 00:00:00 EDT 1988
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Journal Article
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Tue Oct 31 23:00:00 EST 1995
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Related Subjects
520200* -- Environment
Aquatic-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AQUEOUS SOLUTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
DATA
DISPERSIONS
EQUATIONS
EXPERIMENTAL DATA
HALOGENATED ALIPHATIC HYDROCARBONS
INFORMATION
KINETICS
MIXTURES
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PH VALUE
POLLUTION
REACTION KINETICS
SOLUTIONS
WATER POLLUTION
Aquatic-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AQUEOUS SOLUTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
DATA
DISPERSIONS
EQUATIONS
EXPERIMENTAL DATA
HALOGENATED ALIPHATIC HYDROCARBONS
INFORMATION
KINETICS
MIXTURES
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PH VALUE
POLLUTION
REACTION KINETICS
SOLUTIONS
WATER POLLUTION