A comparative temperature-programmed sulfiding study of the HDS catalysts MoO sub 3 /Al sub 2 O sub 3 and WO sub 3 /Al sub 2 O sub 3

Conference · Tue Mar 31 23:00:00 EST 1987 · American Chemical Society, Division of Petroleum Chemistry, Preprints; (USA)

OSTI ID:5111827

Mangnus, P J; Scheffer, B; Moulijn, J A ^[1]

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1. Univ. of Amsterdam (Netherlands)

The most important HDS catalysts are Co-Mo/Al{sub 2}O{sub 3}, Ni-Mo/Al{sub 2}O{sub 3} and Ni-W/Al{sub 2}O{sub 3}. These catalysts are usually prepared as alumina-supported oxides and are sulfided in situ. This process of sulfiding is not completely understood up to now. To understand the sulfiding processes on commercial catalysts it is crucial to investigate the sulfiding process of MoO{sub 3}/Al{sub 2}O{sub 3} and WO{sub 3}/Al{sub 2}O{sub 3}. The TPS technique was chosen because it mimics the practical sulfiding process, and sulfiding of all species is observed quantitatively. The first TPS experiments were performed by Nag et al. Recently, TPS has been successfully applied to MoO{sub 3}/Al{sub 2}O{sub 3}, CoO/Al{sub 2}O{sub 3}, CoO-MoO{sub 3}/Al{sub 2}O{sub 3}, NiO-WO{sub 3}/Al{sub 2}O{sub 3} and Re{sub 2}O{sub 7}/Al{sub 2}{sub 3}.

• OSTI ID: 5111827
• Report Number(s): CONF-8704347--
• Journal Information: American Chemical Society, Division of Petroleum Chemistry, Preprints; (USA), Journal Name: American Chemical Society, Division of Petroleum Chemistry, Preprints; (USA) Vol. 32:2; ISSN 0569-3799; ISSN ACPCA
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020400* -- Petroleum-- Processing
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
COBALT
DATA
DESULFURIZATION
ELEMENTS
EXPERIMENTAL DATA
INFORMATION
METALS
MOLYBDENUM
NICKEL
NUMERICAL DATA
OXIDES
OXYGEN COMPOUNDS
SPECTROPHOTOMETRY
SULFIDATION
TRANSITION ELEMENTS
TUNGSTEN