Water-olefin complexes. A matrix isolation study

Journal Article · Thu Oct 09 00:00:00 EDT 1986 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100412a023· OSTI ID:5109392

Engdahl, A; Nelander, B

The infrared spectra of the H/sub 2/O, HDO, and D/sub 2/O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.

• Research Organization: Univ. of Lund, Sweden
• OSTI ID: 5109392
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 90:21; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
AROMATICS
BENZENE
BUTADIENE
BUTENES
COMPLEXES
CONDENSED AROMATICS
DATA
DIENES
ENERGY LEVELS
ETHYLENE
EXCITED STATES
EXPERIMENTAL DATA
HEAVY WATER
HYDROCARBONS
HYDROGEN COMPOUNDS
INFORMATION
INFRARED SPECTRA
ISOTOPE EFFECTS
MATRIX ISOLATION
NAPHTHALENE
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
POLYENES
PROPYLENE
SPECTRA
ULTRALOW TEMPERATURE
VERY LOW TEMPERATURE
VIBRATIONAL STATES
WATER