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Title: Calcium/calcium chromate thermal battery and thermal battery assignment at the General Electric Neutron Devices Department

Technical Report ·
OSTI ID:5106087

A nontechnical overview of thermal battery design and fabrication methods is given, along with a description of the role of the General Electric Neutron Devices Department (GEND) in the Department of Energy's battery program. A thermal battery is a primary, reserve electrochemical power source; that is, it can be used only once and then for a relatively short period, measured in minutes. To energize the battery, an external electrical signal ignites a heat source in the battery to melt the electrolyte and initiate an electrochemical reaction. The battery is made up of several series-connected cells, each with an anode, a cathode, and a current collector. A cell's anode is calcium; its cathode is hexavalent chromium. The electrochemical reaction takes place when the electrolyte is melted by heat supplied from ignition of an iron-potassium perchlorate disk. Since no reaction occurs while the electrolyte is in the solid state, the battery does not deteriorate with time and has a shelf life exceeding 20 years. Presented are such critical battery operating characteristics as temperature, rise time, active life, current capacity, etc. Design factors described include size and shape, pellet density, ignition methods, anode construction, etc. These batteries are designed by Sandia National Laboratories, Albuquerque. GEND acts as a procurement agency and provides engineering support to suppliers. 18 figures.

Research Organization:
General Electric Co., St. Petersburg, FL (USA). Neutron Devices Dept.
DOE Contract Number:
AC04-76DP00656
OSTI ID:
5106087
Report Number(s):
GEPP-TIS-529
Country of Publication:
United States
Language:
English