Porphyrins. 21. Synthesis and reactivities of 13,17-disubstituted derivatives of 13,17-desethyletioporphyrin III
A method was developed for the preparation, from hemin, of a porphyrin with hydroxypropyl substituents in the 13 and 17 positions of the macroring and a number of its derivatives. The UV and visible spectra of solutions of the compounds in chloroform were recorded with an SF-18 spectrophotometer. The IR spectra of KBr pellets of the compounds were obtained with a Perkin-Elmer 398 spectrometer. The PMR spectra of solutions in CDCl/sub 3/ (with the addition of 5% d/sub 5/-pyridine in the case of the zinc complexes) were recorded with Bruker WM-360 and WM-250 spectrometers with tetramethylsilane (TMS) as the internal standard. The mass spectra were recorded with a Varian MAT-311 spectrometer.
- Research Organization:
- Institute of Biophysics, Moscow (USSR)
- OSTI ID:
- 5099460
- Journal Information:
- Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 23:2; ISSN CHCCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM HYDRIDES
BOROHYDRIDES
BORON COMPOUNDS
CARBOXYLIC ACIDS
CATALYTIC EFFECTS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COMPLEXES
DEUTERIUM COMPOUNDS
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INFRARED SPECTRA
ISOTOPE EFFECTS
LITHIUM COMPOUNDS
LITHIUM HYDRIDES
MASS SPECTRA
NMR SPECTRA
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PORPHYRINS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
ULTRAVIOLET SPECTRA
ZINC COMPLEXES