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Conversion of low-concentration tritium gas to tritiated water

Journal Article · · Fusion Technology; (USA)
OSTI ID:5072357
 [1];  [2];  [3]
  1. Japan Atomic Energy Research Institute, Dept. of Health Physics, Tokai-mura Naka-gun, Ibaraki-ken, 319-11 (JP)
  2. Oak Ridge National Lab., TN (USA). Health and Safety Research Div.
  3. Oak Ridge National Lab., TN (USA). Chemistry Div.
The authors describe the conversion reaction of tritium gas (T/sub 2/) to tritiated water studies experimentally at initial tritium concentrations between 9.6 x 10/sup -3/ and 48 GBq . m/sup -3/ (2.6 x 10/sup -4/ and 1.3 Ci . m/sup -3/) in air. Effects of water vapor and catalysts on the conversion reaction were also examined. Stainless steel, copper, paint, and platinum black were used as potential catalytic surfaces. First-order rate constants for the reaction in air are found to be independent of initial tritum concentration, and there is no effect from water vapor on the reaction. The conversion is insensitive to the presence or absence of stainless steel and copper.
OSTI ID:
5072357
Journal Information:
Fusion Technology; (USA), Journal Name: Fusion Technology; (USA) Vol. 16:2; ISSN 0748-1896; ISSN FUSTE
Country of Publication:
United States
Language:
English