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Elemental mapping at grain boundaries in alloy X-750 by EFTEM

Conference ·
OSTI ID:505347
;  [1];  [2]
  1. Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.
  2. Oak Ridge Inst. for Science and Education, TN (United States)

Alloy X-750 is a {gamma}{prime}-strengthened, nickel-base alloy used in demanding high-temperature applications. The HTH commercial heat treatment condition provides excellent strength and good corrosion resistance. However, the resultant precipitate structure is complex with fine ({approximately}30 nm) intragranular {gamma}{prime} phase and copious intergranular precipitation of at least four phases ({gamma}{prime}, M{sub 23}C{sub 6}, M{sub 23}B{sub 6}, and TiN). The intergranular precipitation causes localized grain boundary migration and results in a convoluted grain boundary structure. Such complex grain boundary microstructures increase the difficulty of phase identification and interfacial composition measurements by traditional analytical electron microscopy methods. Elemental mapping by EFTEM is a useful additional or alternative technique for characterizing such structures. A Gatan Imaging Filter (GIF) on a Philips CM30 (LaB{sub 6}) was used in the current investigation. Experimental details have been summarized elsewhere. Elemental maps of Cr, Ti, and Ni (net L{sub 23} intensities) are presented for a typical grain boundary region of a HTH heat treated specimen.

Research Organization:
Oak Ridge National Lab., TN (United States)
Sponsoring Organization:
USDOE Office of Energy Research, Washington, DC (United States)
DOE Contract Number:
AC05-96OR22464
OSTI ID:
505347
Report Number(s):
CONF-970834--14; ON: DE97005142
Country of Publication:
United States
Language:
English