Kinetics of the reduction of cobalt(III) amine complexes by 1-hydroxy-1-methylethyl radicals
Journal Article
·
· Inorganic Chemistry; (USA)
- Tohoku Univ., Sendai (Japan)
- Iowa State Univ., Ames (USA)
In order to better understand the rate constants for the reduction of several cobalt complexes by 1-hydroxy-1-methylene radicals ({sup {sm bullet}}C(CH{sub 3}){sub 2}OH), the reactions of {sup {sm bullet}}(CH{sub 3}){sub 2}OH with several cobalt(III) complexes of bidentate amines have been studied. The Marcus-Hush theory was deemed the most appropriate for analysis of the kinetic data. The correlation between the kinetics of the reduction of the Co(III) amines by C(CH{sub 3}){sub 2}OH and the reduction of the first d-d band for Co(III) complexes is discussed. 21 refs., 2 figs., 1 tab.
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 5052844
- Journal Information:
- Inorganic Chemistry; (USA), Vol. 28:5; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
Similar Records
Kinetics of reduction of a series of imidazolium ions and cobalt(III)-imidazole complexes by 1-hydroxy-1-methylethyl radicals
Reduction of transition metal complexes by tris(bipyridyl)ruthenium(1+) ion, chromium(II) ion, and the 10-hydroxy-1-methylethyl radical
Reduction of transition metal complexes by tris(bipyridyl)ruthenium(1+) ion, chromium(II) ion, and the 1-hydroxy-1-methylethyl radical
Journal Article
·
Wed Nov 29 00:00:00 EST 1989
· Inorganic Chemistry; (USA)
·
OSTI ID:5052844
+2 more
Reduction of transition metal complexes by tris(bipyridyl)ruthenium(1+) ion, chromium(II) ion, and the 10-hydroxy-1-methylethyl radical
Thesis/Dissertation
·
Tue Jan 01 00:00:00 EST 1985
·
OSTI ID:5052844
Reduction of transition metal complexes by tris(bipyridyl)ruthenium(1+) ion, chromium(II) ion, and the 1-hydroxy-1-methylethyl radical
Technical Report
·
Tue Oct 01 00:00:00 EDT 1985
·
OSTI ID:5052844