Nonreactive collinear close-coupled transition probabilities for N sub 2 + O sub 2 , H sub 2 + Cl sub 2 , and O sub 2 + Cl sub 2 at 0. 5-3. 2 eV
Journal Article
·
· Journal of Physical Chemistry; (USA)
- Univ. of Nebraska, Omaha (USA)
Close-coupled calculations have been carried out in the collinear geometry for N{sub 2} + O{sub 2} (2.0-3.2 eV), H{sub 2} + Cl{sub 2} (0.5-2.0 eV), and O{sub 2} + Cl{sub 2} (0.5-2.0 eV). The nonreactive transition probabilities reported are converged to at least three figures, even for transitions where the change in vibrational quantum number for one or both of the molecules is large or where the initial vibrational quantum numbers are large. These results greatly extend the mass ratio (or ratio of the two molecules, vibrational energy level spacings) for the two colliding species and should prove useful in assessing the accuracy of collision theory approximations.
- OSTI ID:
- 5049818
- Journal Information:
- Journal of Physical Chemistry; (USA), Vol. 93:5; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
Similar Records
Exact quantum mechanical study of kinetic isotope effects in the collinear reaction Cl + H$sub 2$ $Yields$ HCl + H. The H$sub 2$/D$sub 2$ and the H$sub 2$/T$sub 2$ isotope effects
Exact quantum study of vibrational deactivation by reactive and nonreactive collisions in the collinear isotopic H + FH systems. Interim report. [H + FH, D + FD, H + FD, D + FH]
Collinear diatomic molecule-diatomic molecule collisions treated in the sudden approximation
Journal Article
·
Tue Jan 01 00:00:00 EST 1974
· J. Chem. Phys., v. 60, no. 1, pp. 133-136
·
OSTI ID:5049818
Exact quantum study of vibrational deactivation by reactive and nonreactive collisions in the collinear isotopic H + FH systems. Interim report. [H + FH, D + FD, H + FD, D + FH]
Technical Report
·
Sun Aug 01 00:00:00 EDT 1976
·
OSTI ID:5049818
Collinear diatomic molecule-diatomic molecule collisions treated in the sudden approximation
Journal Article
·
Thu Jun 15 00:00:00 EDT 1989
· Journal of Physical Chemistry; (USA)
·
OSTI ID:5049818
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
54 ENVIRONMENTAL SCIENCES
CHLORINE COMPOUNDS
MOLECULE COLLISIONS
HYDROGEN COMPOUNDS
NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
ENERGY TRANSFER
ENERGY-LEVEL TRANSITIONS
EV RANGE 01-10
MATHEMATICAL MODELS
MILLI EV RANGE
QUANTUM MECHANICS
SCATTERING
THEORETICAL DATA
VIBRATIONAL STATES
COLLISIONS
DATA
ENERGY LEVELS
ENERGY RANGE
EV RANGE
EXCITED STATES
HALOGEN COMPOUNDS
INFORMATION
MECHANICS
NUMERICAL DATA
400201* - Chemical & Physicochemical Properties
540110
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
54 ENVIRONMENTAL SCIENCES
CHLORINE COMPOUNDS
MOLECULE COLLISIONS
HYDROGEN COMPOUNDS
NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
ENERGY TRANSFER
ENERGY-LEVEL TRANSITIONS
EV RANGE 01-10
MATHEMATICAL MODELS
MILLI EV RANGE
QUANTUM MECHANICS
SCATTERING
THEORETICAL DATA
VIBRATIONAL STATES
COLLISIONS
DATA
ENERGY LEVELS
ENERGY RANGE
EV RANGE
EXCITED STATES
HALOGEN COMPOUNDS
INFORMATION
MECHANICS
NUMERICAL DATA
400201* - Chemical & Physicochemical Properties
540110