Mechanistic aspects of metal-catalyzed alternating copolymerization of olefins with carbon monoxide
Journal Article
·
· Accounts of Chemical Research; (United States)
- Pennsylvania State Univ., University Park, PA (United States)
Three different synthetic methods have been developed for the copolymerization of olefins with carbon monoxide. The copolymerization may be initiated by free radicals or induced by [gamma]-rays. A number of transition metal complexes are also effective catalysts for the copolymerization reaction. The metal-catalyzed copolymerization procedure has several noteworthy advantages over the other two. First, the copolymerization occurs at significantly lower pressures and at or below ambient temperature. Second, the resultant polymers have a strictly alternating structure and high molecular weights. 31 refs., 4 figs., 1 tab.
- OSTI ID:
- 5042178
- Journal Information:
- Accounts of Chemical Research; (United States), Journal Name: Accounts of Chemical Research; (United States) Vol. 26:6; ISSN 0001-4842; ISSN ACHRE4
- Country of Publication:
- United States
- Language:
- English
Similar Records
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Journal Article
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Sun Feb 28 23:00:00 EST 1993
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·
OSTI ID:6482873
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Journal Article
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Wed Apr 26 00:00:00 EDT 1995
· Journal of the American Chemical Society
·
OSTI ID:45025
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Sun Nov 20 23:00:00 EST 1994
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
COPOLYMERIZATION
HOMOGENEOUS CATALYSIS
HYDROCARBONS
NICKEL COMPLEXES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PALLADIUM COMPLEXES
POLYMERIZATION
RHODIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
COPOLYMERIZATION
HOMOGENEOUS CATALYSIS
HYDROCARBONS
NICKEL COMPLEXES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PALLADIUM COMPLEXES
POLYMERIZATION
RHODIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES