Reaction between methane and carbon tetrachloride

Journal Article · Sat Oct 01 04:00:00 EDT 1983 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:5031882

Rozanov, V N; Rozlovskii, A I; Treger, Y A; Babich, N F

Processes occurring in CH/sub 4/ + CCl/sub 4/ + Ar mixtures were studied in a flow-type reactor at 450-525/sup 0/C and atmospheric pressure over a reaction time Tav = 4.94 sec for the initial compositions in the content variation ranges: CCl/sub 4/ 8.4-29.5, CH/sub 4/ 22.1-57.2, and Ar 18.0-51.4%. The contents of chlorinated organic components and argon in the final mixture of the reaction products were determined chromatographically, and those of chlorine and hydrogen chloride, by absorption with a potassium iodide solution followed by titration (in one sample) with hyposulfite and alkali. In addition to unreacted initial components, the reaction products contained CH/sub 3/Cl, CH/sub 2/Cl/sub 2/, CHCl/sub 3/, C/sub 2/H/sub 2/CL/sub 2/, C/sub 2/Cl/sub 4/, C/sub 2/CL/sub 6/, HCl, and Cl/sub 2/. 2 tables.

• OSTI ID: 5031882
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Phys. Chem. (Engl. Transl.); (United States) Vol. 269:4; ISSN DKPCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400800 -- Combustion
Pyrolysis
& High-Temperature Chemistry
ALKANES
ARGON
CARBON TETRACHLORIDE
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE
CHLOROFORM
CHROMATOGRAPHY
DATA
ELEMENTS
EXPERIMENTAL DATA
FLUIDS
GAS CHROMATOGRAPHY
GASES
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENS
HIGH TEMPERATURE
HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFORMATION
INORGANIC ACIDS
KINETICS
METHANE
METHYL CHLORIDE
METHYLENE CHLORIDE
NONMETALS
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
QUANTITY RATIO
RARE GASES
REACTION KINETICS
SEPARATION PROCESSES
TEMPERATURE DEPENDENCE
TITRATION
YIELDS