Synthesis of fullerene amino acid derivatives by direct interaction of amino acid ester with C{sub 60}
Journal Article
·
· Journal of Organic Chemistry
OSTI ID:501784
- Peking Univ., Beijing (China); and others
Refluxing C{sub 60} together with glycine ethyl ester yields C{sub 60}(Me{sub 2}CHNHCHCOOEt) (1) while under photochemical activation, the major product is C{sub 60}(EtOOCCHNHCCOOEt) (2b). Photochemical activation of C{sub 60} in the presence of sarcosine esters gives C{sub 60}(CH{sub 2}N(Me)CHCOOR) (3) C{sub 60}(ROOCCHNHCHCOOR) (2) (R = Me, Et, CH{sub 2}Ph). The esters do not hydrolyze easily in mineral acid containing solutions.
- OSTI ID:
- 501784
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 6 Vol. 61; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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