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Two angle dependent reactive infinite order sudden approximation

Journal Article · · J. Chem. Phys.; (United States)
DOI:https://doi.org/10.1063/1.447126· OSTI ID:5013162
The reactive infinite order sudden approximation is redeveloped in a manner in which the initial and final arrangement internal angles ..gamma../sub lambda/ amd ..gamma../sub ..nu../ enter as independent quantities. The analysis follows parallel to that due to Khare, Kouri, and Baer except that matching of the wave function from different arrangements is done in a manner such that no single ..gamma../sub ..nu../ angle is associated with a particular ..gamma../sub lambda/ angle. As a consequence, the matching surface parameter B/sub lambdanu/ does not occur.
Research Organization:
Department of Chemistry and James Franck Institute, University of Chicago, Chicago, Illinois 60637
OSTI ID:
5013162
Journal Information:
J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 80:7; ISSN JCPSA
Country of Publication:
United States
Language:
English

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