Photoelectron photoion molecular beam spectroscopy
The use of supersonic molecular beams in photoionization mass spectroscopy and photoelectron spectroscopy to assist in the understanding of photoexcitation in the vacuum ultraviolet is described. Rotational relaxation and condensation due to supersonic expansion were shown to offer new possibilities for molecular photoionization studies. Molecular beam photoionization mass spectroscopy has been extended above 21 eV photon energy by the use of Stanford Synchrotron Radiation Laboratory (SSRL) facilities. Design considerations are discussed that have advanced the state-of-the-art in high resolution vuv photoelectron spectroscopy. To extend gas-phase studies to 160 eV photon energy, a windowless vuv-xuv beam line design is proposed.
- Research Organization:
- California Univ., Berkeley (USA)
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 5002371
- Report Number(s):
- LBL-11434
- Country of Publication:
- United States
- Language:
- English
Similar Records
Atomic photoelectron-spectroscopy studies using synchrotron radiation
Photoionization and photoelectron spectroscopy of molecular Rydberg states
Multiplexed characterization of complex gas-phase mixtures combining chirped-pulse Fourier transform microwave spectroscopy and VUV photoionization time-of-flight mass spectrometry
Technical Report
·
Mon Jan 31 23:00:00 EST 1983
·
OSTI ID:6182582
Photoionization and photoelectron spectroscopy of molecular Rydberg states
Thesis/Dissertation
·
Thu Dec 31 23:00:00 EST 1987
·
OSTI ID:5180077
Multiplexed characterization of complex gas-phase mixtures combining chirped-pulse Fourier transform microwave spectroscopy and VUV photoionization time-of-flight mass spectrometry
Journal Article
·
Wed Sep 05 20:00:00 EDT 2018
· Review of Scientific Instruments
·
OSTI ID:1540250
Related Subjects
640301* -- Atomic
Molecular & Chemical Physics-- Beams & their Reactions
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
BEAMS
BREMSSTRAHLUNG
ELECTROMAGNETIC RADIATION
ELECTRON SPECTROSCOPY
ENERGY LEVELS
EXCITED STATES
EXTREME ULTRAVIOLET RADIATION
FLUID FLOW
IONIZATION
MASS SPECTROSCOPY
MOLECULAR BEAMS
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
RADIATIONS
RELAXATION
ROTATIONAL STATES
SPECTROSCOPY
SUPERSONIC FLOW
SYNCHROTRON RADIATION
ULTRAVIOLET RADIATION
Molecular & Chemical Physics-- Beams & their Reactions
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
BEAMS
BREMSSTRAHLUNG
ELECTROMAGNETIC RADIATION
ELECTRON SPECTROSCOPY
ENERGY LEVELS
EXCITED STATES
EXTREME ULTRAVIOLET RADIATION
FLUID FLOW
IONIZATION
MASS SPECTROSCOPY
MOLECULAR BEAMS
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
RADIATIONS
RELAXATION
ROTATIONAL STATES
SPECTROSCOPY
SUPERSONIC FLOW
SYNCHROTRON RADIATION
ULTRAVIOLET RADIATION