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Studies of Y-Ba-Cu-O single crystals by x-ray absorption spectroscopy

Conference · · AIP Conference Proceedings (American Institute of Physics); (United States)
OSTI ID:5001540
; ;  [1]; ; ;  [2];  [3]; ;  [4]; ;  [5];  [6]
  1. Department of Physics, SUNY at Buffalo, NY 14260 (United States)
  2. Kernforschungszentrum Karlsruhe, Institut fuer NukleareFestkoerperpysik, Postfach 3640, W-7500 Karsruhe (Germany)
  3. Brookhaven National Laboratory, Upton, NY 11973 (United States)
  4. Universitaet Karlsruhe, Institut fuer Kristallchemie, W-7500 Karsruhe (Germany)
  5. Labor fuer Festkoerperphysik, ETH Zuerich, Hoenggerberg/HPF, CH 8093 Zuerich (Switzerland)
  6. Walter-Meiner-Institut, W-8046 Garching (Germany)
The symmetry and density of unoccupied states of YBa{sub 2}Cu{sub 3}O{sub 7} and YBa{sub 2}Cu{sub 4}O{sub 8} have been investigated by orientation dependent x-ray absorption spectroscopy on the O 1s edge using a bulk-sensitive fluorescence yield-detection method. It has been found that the O 2{ital p} holes are distributed equally between the CuO{sub 2} planes and CuO chains and that the partial density of unoccupied O 2{ital p} states in the CuO{sub 2} planes are identical in both systems investigated. The upper Hubbard band has been observed in the planes but not in the chains in both systems.
OSTI ID:
5001540
Report Number(s):
CONF-9109102--
Conference Information:
Journal Name: AIP Conference Proceedings (American Institute of Physics); (United States) Journal Volume: 251:1
Country of Publication:
United States
Language:
English