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Stability of viscoelastic dynamic contact lines: An experimental study

Journal Article · · Physics of Fluids (1994)
DOI:https://doi.org/10.1063/1.869480· OSTI ID:495864
;  [1]
  1. Department of Chemical Engineering, Stanford University, Stanford, California 94305 (United States)

An experimental study of the rivulet instability associated with spin coating a circular drop of fluid is conducted to examine the effect of elasticity on the onset and evolution of the instability. The spin coating experiments are conducted with viscoelastic drops consisting of a high molecular weight polystyrene in tricresyl phosphate (TCP), as well as the Newtonian solvent TCP. Results show an unequivocal delay in the onset of the instability when the appropriate Weissenberg number is sufficiently large, resulting in a larger coated area and more finger arms relative to Newtonian results. Experiments performed with the viscoelastic fluid at low Weissenberg number exhibit similar behavior to those performed with the Newtonian solvent as expected. Additionally, the growth rate of the instability is reduced for experiments in which the elastic forces are important, in agreement with the perturbation theory of Spaid and Homsy [Phys. Fluids {bold 8}, 460 (1996)], demonstrating that elastic forces have a stabilizing influence on the contact line instability. {copyright} {ital 1997 American Institute of Physics.}

DOE Contract Number:
FG03-87ER13673
OSTI ID:
495864
Journal Information:
Physics of Fluids (1994), Journal Name: Physics of Fluids (1994) Journal Issue: 4 Vol. 9; ISSN PHFLE6; ISSN 1070-6631
Country of Publication:
United States
Language:
English

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