1,1,1-Trimethylhydrazinium iodide: A novel, highly reactive reagent for aromatic amination via vicarious nucleophilic substitution of hydrogen
Journal Article
·
· Journal of Organic Chemistry
- Lawrence Livermore National Lab., CA (United States)
1,1,1-Trimethylhydrazinium iodide, TMHI, has been shown to be a novel vicarious nucleophilic substitution aminating reagent. It can be used to obtain isomers not produced by reaction with other nucleophilic aminating reagents. It is easily prepared from 1,1-dimethylhydrazine, or directly from hydrazine. Further studies on the use of TMHI and related quaternary hydrazines as nucleophlic aminating reagents are in progress. 1 tab.
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 494236
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 9 Vol. 61; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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