Relaxometric, structural, and dynamic NMR studies of DOTA-like Ln(III) complexes (Ln = La, Gd, Ho, Yb) containing a p-nitrophenyl substituent
- Universita di Torino (Italy); and others
Complexes of La(III), Gd(III), Ho(III), and Yb(III) with the novel ligand, 1-((p-nitrophenyl)carboxymethyl)-4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecane were prepared. The complexes were studied by NMR spectroscopy with an emphasis toward comparisons to the closely related Ln(III)(DOTA) complexes. Relaxivity of these complexes under NMR conditions was ascertained and studies of molecular structure and dynamics were discussed.
- OSTI ID:
- 486448
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 10 Vol. 35; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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