COMPLEX IONS IN FUSED SALTS. CADMIUM AND LEAD BROMIDES
Journal Article
·
· Journal of Physical Chemistry (U.S.)
OSTI ID:4840954
The bromo-complexes of lead and cadmium were studied by following the emf of a concentration cell as a function of metal ion concentration. This was done at various initial bromide ion concentrations and several temperatures. The results show that the mono- and tri-bromo species in the cadmium system are thermodynamically important although the formation constants exhibit a definite temperature dependence. It is shown that deviations from ideal behavior in reciprocal molten salt solutions can be ascribed to complex ion formation. When applied to the experimental data the chemical and lattice-model approaches are hardly distinguishable. The data are tabulated. (P.C.H.)
- Research Organization:
- Ames Lab., Ames, Iowa
- NSA Number:
- NSA-15-030675
- OSTI ID:
- 4840954
- Report Number(s):
- IS-228; 0022-3654
- Journal Information:
- Journal of Physical Chemistry (U.S.) , Journal Name: Journal of Physical Chemistry (U.S.) Vol. Vol: 65; ISSN JPCHA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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