OXIDATION RATE OF RUTHENIUM (4+) NITRATE AND RUTHENIUM (4+) HYDROXYCHLORIDE IN WATER SOLUTIONS BY OZONE (in Russian)
Journal Article
·
· Vestnik Leningrad. Univ., 16: No. 4, Ser. Fiz. i Khim.
OSTI ID:4840931
The oxidation rate of simple ruthenium compounds in water solutions by ozonized oxygen was studied. At equilibrium the reaction is of zero order. At high concentrations of nitnic and especially of hydrochloric acid the oxidation rate is strongly lowered due to the formation of strong complex compounds. At low temperatures and high concentrations of nitric acid, step-by-step oxidation through unstable, probably hexavalent, states having a bright emerald-green color is observed. (tr-auth)
- Research Organization:
- Originating Research Org. not identified
- NSA Number:
- NSA-15-030686
- OSTI ID:
- 4840931
- Journal Information:
- Vestnik Leningrad. Univ., 16: No. 4, Ser. Fiz. i Khim., Journal Name: Vestnik Leningrad. Univ., 16: No. 4, Ser. Fiz. i Khim. Vol. Vol: No. 1
- Country of Publication:
- Country unknown/Code not available
- Language:
- Russian
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