The Electrode Potential of Ruthenium(IV) and Its Lower Oxidation States
Journal Article
·
· Journal of the American Chemical Society
From titration data obtained for the reduction of ruthenium(IV) perchlorate with vanadium(II) sulfate, the electrode potentials of Ru(IV) and Ru(III) were calculated. The existence of a state with oxidation number 3.5 was confirmed. In the polarographic reduction of Ru(IV) in perchloric acid solutions three waves were observed and the dependence of the half-wave potentials on pH was determined. Both monomeric and polymeric Ru(IV) species were studied. (auth)
- Research Organization:
- Purdue Univ., Lafayette, Ind.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-16-025343
- OSTI ID:
- 4828248
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 14 Vol. 84; ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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