Control of photosubstitution in dinuclear ruthenium polypyridyl complexes by choice of bridging ligand
- Dublin City Univ. (Ireland)
Photochemical studies of [(Ru(bpy){sub 2}){sub 2}(bpzt)]{sup 3+} are discussed. The results are compared with earlier studies on complexes containing the 3,5`-bis(pyridin-2-yl)-1,2,4-triazole (Hbpt). Differences in the {pi}{sup *} levels in Hbpt versus Hbpzt ligands alter the location of the LUMO for the complexes. The objective of these studies is to investigate the photochemistry of these complexes.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 482365
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 15 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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