THE COMPOSITION OF SOME NITRATO NITROSYLRUTHENIUM COMPLEXES

Journal Article · Fri Dec 01 04:00:00 EST 1961 · J. Inorg. & Nuclear Chem.

DOI:https://doi.org/10.1016/0022-1902(61)80277-7· OSTI ID:4811058

Wallace, R M

Isolation and analysis of some of the nitrato complexes of nitrosylruthenium existing in nitric acid solutions has permitted identification of the complexes. The complex that is most extractable in tri-n-butyl phosphate (TBP) was shown to be trinitrato nitrosylruthenium STARuNO(NO/sub 3/)/sub 3/ (H/ sub 2/O)/sub w2/!; other extractable species contained fewer than three nitrato groups. Three cationic species, which were isolated by ion exchange techniques, were shown to be dinitrato, mononitrato, and nonnitrato nitrosylruthenium with the probable formuias STARuNO(NO/sub 3/)/sub3/H/sub 2/O) /sub 3/!/sup +/, STARuNO(NO/sub 3/) (H/sub 2/O)/sub 4!/sup 2+, and STARuNO(H/sub 2/O)/sub 5/!/sup 3+/ respectively. A study of the complexes adsorbed by anion exchange resins indicated the absorbed species to be a mixture of complexes some of which contained more than three nitrato groups per ruthenium atom. (auth)

• Research Organization: E.I. du Pont de Nemours & Co., Aiken, S.C.
• NSA Number: NSA-16-010013
• OSTI ID: 4811058
• Journal Information: J. Inorg. & Nuclear Chem., Journal Name: J. Inorg. & Nuclear Chem. Vol. Vol: 20
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ABSORPTION
ANGULAR MOMENTUM
ANIONS
BUTYL PHOSPHATES
CATIONS
CHEMISTRY
COMPLEXES
ENERGY
INTERACTIONS
ION EXCHANGE
JOURNAL
MIXING
MOMENTUM
NITRATES
NITRIC ACID
NITRIDES
NITRITES
NITROGEN OXIDES
NUCLEAR MODELS
NUCLEAR RADII
NUCLEAR REACTIONS
NUCLEAR STRUCTURE
NUCLEAR THEORY
NUCLEI
ORGANIC NITROGEN COMPOUNDS
PERTURBATION THEORY
PHOSPHATES
QUALITATIVE ANALYSIS
QUANTUM MECHANICS
RESINS
RUTHENIUM
RUTHENIUM COMPLEXES
SAMPLING
SCATTERING
SEPARATION PROCESSES
SOLUTIONS
SOLVENT EXTRACTION