THE EFFECT OF THE H$sub 2$-H$sub 2$O ISOTOPE EXCHANGE AT THE SURFACE OF THE (Pd - H)cap alphas ELECTRODE ON ITS POTEENTIAL (in German)
Journal Article
·
· Acad. rep. populaire Roumaine, Rev. phys.
OSTI ID:4807708
In order to investigate the effect of isotope exchange between hydrogen and heavy water on the potential of the (PdH)/sub alpha s/ electrode, measurements were made in H/sub 2/H/sub 2/SO/sub 4/ and H/sub 2//(D/sub 2/PO/sub 4/ + H/sub 3/PO/sub 4/). The experimental method is briefly described and the results are discussed. The results lead to the conclusion that the isotope effect on the potential of the (Pd-H)/ alpha s/ electrode is additive and amounts to DELTA E = 0.01992 v for 100 mole% deuterium at 30% C. The isotope exchange- absorption reaction between hydrogen and heavy water in the presence of metallic Pd leads to the same isotope distribution in the metal and in the solution. (J.S.R.)
- Research Organization:
- Originating Research Org. not identified
- NSA Number:
- NSA-16-026971
- OSTI ID:
- 4807708
- Journal Information:
- Acad. rep. populaire Roumaine, Rev. phys., Journal Name: Acad. rep. populaire Roumaine, Rev. phys. Vol. Vol: 6
- Country of Publication:
- Country unknown/Code not available
- Language:
- German
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