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COMPLEX FORMATION OF ZIRCONIUM WITH ORGANIC ACID ANIONS IN SOLUTIONS (in Russian)

Journal Article · · Zhur. Neorg. Khim.
OSTI ID:4791044
The formation of zirconium complexes in oxalic, malonic, succinic, and tartaric acids was analyzed. In Zr(IV) oxalates, malonates, and succinates the addend- metal ratio is 1 : 1, while the tartarates form two compounds. Complex zirconium tartarates and succinates possess a catalytic activity. The nominal equilibrium constants are calculated for the formation of STAZr(OH)C/sub 2/O/sub 4/!, STAZr(OH)/sub 3/ C/sub 3/H/sub 2/O/sub 4/!/sub -/, STAZr(OH)C/sub 4/H/sub 4/ O/sub 4/! p +/, and STAZr(C/sub 4/ H/sub 4/O/sub 6/)/sub 2/!. (R.V.J.)
Research Organization:
Ivanov Inst. of Chemistry and Tech., USSR
NSA Number:
NSA-16-011676
OSTI ID:
4791044
Journal Information:
Zhur. Neorg. Khim., Journal Name: Zhur. Neorg. Khim. Vol. Vol: 6
Country of Publication:
Country unknown/Code not available
Language:
Russian

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